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-   -   Why doesn't TC-4 have a copper top? (http://forums.procooling.com/vbb/showthread.php?t=6014)

jaydee 03-20-2003 02:05 PM

There is a difference between metal to metal (brass barbs used in aluminum threads) and metal to water to metal (copper block, hose with water, aluminum rad). I would theroize that metal to metal would increase corrosion time considerably.

bigben2k 03-20-2003 02:18 PM

Quote:

Originally posted by dacooltech
BigBen2k - Silkolene ProCCA looks very interesting. I remember Hmale mentioning it some time ago, but guess i didn't pay too much attention to it. Thanks for pointing it out :)

Bruce

Looking forward to your comments, Bruce! Silkolene ProCCA has the drawback of being fairly expensive, but bought in larger quantities, heck even in bulk, it might be a good competitor to WW and/or Zerex.

Maybe I'll try calling that Florida outfit, to see if their shipping rates are any lower.

dacooltech 03-20-2003 03:27 PM

Quote:

Looking forward to your comments, Bruce! Silkolene ProCCA has the drawback of being fairly expensive, but bought in larger quantities, heck even in bulk, it might be a good competitor to WW and/or Zerex.
The thing that sounds really nice to me is 1% mixture. This doesn't reduce the efficiency of the water at all.

Yes it's pretty expensive BigBen2K.
But probably by placing a large order we can get better pricing.

BTW Hmale is sending me more than I need for testing. If you just send me your address i can send you some.
BillA- I'll send you some too, so that you can check it out.

bigben2k 03-20-2003 03:38 PM

kewl:cool: you have PM with my coordinates.

BillA 03-20-2003 03:57 PM

thanks Bruce
my sys is 2.5 gal

bigben2k 03-20-2003 04:02 PM

If there isn't enough to go around, give my share to Bill.

jaydee 03-20-2003 04:03 PM

Quote:

Originally posted by jaydee116
There is a difference between metal to metal (brass barbs used in aluminum threads) and metal to water to metal (copper block, hose with water, aluminum rad). I would theroize that metal to metal would increase corrosion time considerably.
I guess I should have made this look like more of a question? Anyway any idea if I am wrong or right?

Fixittt 03-20-2003 04:12 PM

your wrong


plain and simple, dont ask me why, but you are.

bigben2k 03-20-2003 04:12 PM

Well, if what you're asking is if the water is helping the corrosion, the answer is yes.

Metal-to-metal, there would be corrosion, but in a dry environment, it wouldn't be noticeable. Put it in water though, or outside... and it'll turn brown/green/blue/whatever faster than...

With the metals not touching, the water would act as an electrolyte. Wether the water is tap or distilled or deionized won't make a difference (except if you're able to maintain deionized water, which is apparently very hard).

Now put in an additive, and you'll have a reduced electrical resistance, which will accelerate the process.

It's a good question.

jaydee 03-20-2003 04:47 PM

Thats what I am saying, where the two metals are connected and then water on it it would corrode faster. When you thread the barbs in the block there is always exposed barb at the bottom of ther hole and water can seep up the threads untill it hits the sealant. I would think, and all my Al blocks with brass barbs seem to show it, that in that spot the corrosion would be the worst. That is where the corrosion started in my last AL block and it was not pretty.

Examples:
Pulled this from one of my threads. This was posted by Cathar.
Quote:

Copper mixed with aluminium...why risk it? You know it's bad news, so why?

Some pretty pictures of a nickel plated aluminium top on a copper base after a couple of months using a mix of radiator corrosion inhibitor and distilled water:
http://home.kooee.com.au/draebor/ima.../corroded2.jpg


My last bock:

http://www.customcooledpc.com/oldblocks/001.jpg
.......................................
This one os the spot to where it is almost through the base. Hard to tell from the pic though.
http://www.customcooledpc.com/oldblocks/002.jpg
.......................................
http://www.customcooledpc.com/oldblocks/003.jpg
.......................................
http://www.customcooledpc.com/oldblocks/004.jpg
.......................................
http://www.customcooledpc.com/oldblocks/005.jpg
.......................................
http://www.customcooledpc.com/oldblocks/006.jpg


Problems were the worst around the barbs.

dacooltech 03-20-2003 07:07 PM

Quote:

thanks Bruce
my sys is 2.5 gal
hrmm 2.5gal.
94.64ml should be enough then. ok i'll send you 100ml :)

Quote:

If there isn't enough to go around, give my share to Bill.
Guess Humberto is sending me around 400oz of this stuff. So should be enough for everyone.

Jaydee116 - Are you trying to scare the n00bies? LOL

Good ole' battery effect ;) BigBen explained it perfectly.
Edit: See BillA's reply below

BTW I wouldn't be too surprised if the US version of Cathar's WW will be offered with an anodized aluminum top too. We'll see ;)

BillA 03-20-2003 07:21 PM

the corrosion shown is not galvanic
the correct name is cell corrosion, aka pitting corrosion
it is the functioning of a small cell in the presence of an electrolyte (the small cell becoming larger over time)
there was an excellent thread on corrosion on overclockers (perhaps someone has a link)

thanks for the inhibitor
thanks to Humberto also

Les 03-20-2003 07:32 PM

Quote:

Originally posted by unregistered

there was an excellent thread on corrosion on overclockers (perhaps someone has a link)

http://forum.oc-forums.com/vb/showth...hreadid=154570

dacooltech 03-20-2003 09:26 PM

thx Bill

Corrosion links (Click!)

Found lots of useful info over @ corrosion-doctors.org

Pitting Corrosion

Galvanic Corrosion

jaydee 03-20-2003 09:29 PM

Quote:

Originally posted by dacooltech


Jaydee116 - Are you trying to scare the n00bies? LOL
Good ole' battery effect ;) BigBen explained it perfectly.


Hell I am still a n00bie so why not. ;)

dacooltech 03-20-2003 11:02 PM

Quote:

quote:Originally posted by Jaydee116

Hell I am still a n00bie so why not.
LOL :)

TerraMex 03-21-2003 02:24 AM

but...
 
Good enough topic to shoot a dumb question.

I've read some time ago that someone (no, i dont get any more ambiguous than this) earthed the waterblock (connected it to the ground of the case) and got some results out of it.

I find it hard to belive, but asking doesnt hurt ... much.

MadDogMe 03-21-2003 03:34 AM

It did'nt pan out enough to get a 'definative' result IIRC, but some people claimed it increased their overclock by a small (IMO) margine...

*****************************************

Quote:

quote:
--------------------------------------------------------------------------------
Originally posted by jaydee116
There is a difference between metal to metal (brass barbs used in aluminum threads) and metal to water to metal (copper block, hose with water, aluminum rad). I would theroize that metal to metal would increase corrosion time considerably.
--------------------------------------------------------------------------------


I guess I should have made this look like more of a question? Anyway any idea if I am wrong or right?
I took it for granted that it did, water is'nt a 'perfect carrier/conductor' is it?. if not then bringing the two closer together can only antagonise it?...

That's my surmise anyway, why I took it for granted...

Pug 03-21-2003 08:28 AM

Quote:

Originally posted by unregistered
I agree that aluminum can work well, with a corrosion inhibitor of course
and my personal preference in inhibitors is certainally one of the glycols at 20% or so

still would like to find a (good) non-glycol inhibitor though

Ethylene Glycol is a no-no -
Quote:

Ethylene glycol, the commonly sold coolant, is a toxic chemical that turns into a corrosive compound as it decomposes !
(from http://www.neosyntheticoil.com/coolant.htm )
but are there any downsides with Propylene Glycol?

I personally use Silkolene Pro Cool (as the one I referred to in my earlier post).

BTW, hi Mark - didn't spot your name on the thread till now... :)

bigben2k 03-21-2003 08:42 AM

For those that don't know, ProCool, as opposed to ProCCA, contains propylene glycol, as well as the corrosion inhibitor.

ProCCA is strictly the inhibitor.

Does anyone have an opinion on this additive, considering the contents?

again:
Highly refined mineral oil: 40 - 50%
Diethoxyethanol: <5%
Fatty Alcohol ethoxylate: <5%
Sodium Sulphonate: 5 - 15%

Pug 03-21-2003 08:43 AM

Quote:

Originally posted by jaydee116
I guess I should have made this look like more of a question? Anyway any idea if I am wrong or right?
I forgot to mention -
I did some testing once with my waterchiller in a tap water/antifreeze environment at subzero temps.
I did observe that the corrosion was much more prevalent where the mixed metals were in contact (alu, copper and mild steel) underwater.
So I'm currently siding with Ben and MadDogMe on this one but am interested to know the basis for Fixitt's reservations. :)


Regards grounding between (alu) rad and (copper) block, I should add that with my setup, my rad is not earthed to the case (plexi rad mount) so this may be a factor that I hadn't taken into consideration in my earlier post.

MadDogMe 03-22-2003 03:21 AM

The thing I read was just about grounding the block to the case IIRC, not to the rad. It was for CPU stability/overclocking as well, not Galvanic corrosion(if that's what you're thinking?)...

RickCain 03-22-2003 10:48 PM

My god... I think Fixitt is right. Who gives a rats ass what the block is gonna look like in two years. IF your are really into water cooling you will upgrade at least twice a year and wouldn't really care about anything other than how much further you can push your rig with the new configuration. IF you know what your doing you will not use tap water thus this entire thread is useless. The list goes no....

Lets have more constructive conversations instead of everyone rushing to their encyclopedia to act like they know what they are talking about only to over analyze everything. This isn't rocket science guys, it's plain old water cooling. :shrug:

[/rant]

BillA 03-22-2003 11:05 PM

RickCain
yours is a good teener approach, lots of that on the hard forums
need a link ?
no one is forcing YOU to think, or learn anything

some here have commercial interests, some don't wish to fill their rad with corrosion product, and some just want to know
different strokes fella

your back button work ?

theetruscan 03-22-2003 11:14 PM

Quote:

Originally posted by RickCain
IF you know what your doing you will not use tap water thus this entire thread is useless. [/rant]

Ok, Rick, as BillA kindly pointed out, if you don't want to know, you didn't have to read it in the first place. Also, are you telling me I'm not a real watercooler unless I junk my LRWW 3-4 months from now? sorry then, I've never really been good at these kinds of things.

Just for the record, what the deuce does using distilled water do to negate the effects of galvanic corrosion. I'm really confused. I'm sure I don't really need to know, but I wouldn't mind clarification, cause saving the headache of picking an anti-corrosive agent would be kinda nice.


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