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-   -   Using Zinc to combat electrolysis (http://forums.procooling.com/vbb/showthread.php?t=10722)

jman1310 10-17-2004 06:47 PM

Using Zinc to combat electrolysis
 
Has anyone tried using sacrificial metal to eliminate galvanic corrosion?
It would require bonding all metal parts in the cooling system together and to a zinc that is immersed in the cooling fluid. Zinc being the softest and weakest metal, it would get corroded first and "sacrifice" itself for the system.

Weak points include: where would the zinc precipitate, regular maintance of the zinc (if it gets heavily corroded it's ability to sacrifice itself is reduced), and the inconvience of bonding the system.

bonding = connecting the cooling system with wire, possibly the case could be used as a common ground

similiar systems are used on boats to prevent galvanic corrosion on gear in direct contact with water

jman

AngryAlpaca 10-17-2004 06:49 PM

Zinc is higher on the electrochemical series. It'd own aluminum ever so slowly. Choose between Magnesium, Sodium (bad), Lithium(bad), Calcium and Potassium.

jman1310 10-17-2004 07:08 PM

ah, well aluminum isn't normally used on the running gear of a boat so I didn't know that!
but what of the question in general, is a sacrificial metal a good idea?

AngryAlpaca 10-17-2004 07:12 PM

Well, aluminum is really the only thing that corrodes in our systems. You can just avoid it. That's the easiest way.

Kobuchi 10-18-2004 01:59 AM

Quote:

Originally Posted by AngryAlpaca
Zinc is higher on the electrochemical series. It'd own aluminum ever so slowly.

Own? Aluminum eats zinc, but yes slowly.
Quote:

Originally Posted by jman1310
ah, well aluminum isn't normally used on the running gear of a boat so I didn't know that!
but what of the question in general, is a sacrificial metal a good idea?

I actually have a workhorse powerboat made entirely of unpainted aluminum. On second thought, I think the steering cable to the outboard is steel... *shudders*. I've never seen aluminum used deliberately in craft without aluminum hulls.

Is a sacrificial metal a good idea? Nothing that would react quickly, I think. We don't want haze and particles. I wouldn't add a third metal like zinc to give copper better fodder than aluminum, because copper will just chew into that zinc and make a mess. With steel bridges and cranes we don't mind a bar of zinc crumbling in the elements, but inside a closed cooling loop we do.

I would consider a sacrificial metal if very slow to corrode - and in practice this means it wouldn't be a third metal but a second. This seems pointless until we consider that the cathode metal of a galvanic couple corrodes less slowly than just by itself. An all copper & brass loop might benefit from, say, tin. The tin would act as a weak corrosion inhibitor.


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