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Originally Posted by bigben2k
No, the acrylic is still an isolator, depending on the variation of the acrylic of course (check the specs): you cannot ground a PSU through a piece of acrylic. (and yes, you want the PSU to be grounded).
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Correct me if I'm wrong but I'm pretty sure that a PSU is grounded through the power cord.
Todd
EDIT: Regardless of the case material, everything plugged in to the PSU is grounded.