Another thought on using high voltage power in a PC:
The case of all PCs (except plastic ones of course) is connected to the AC earth ground through the power supply. Earth ground is connected to the power supply output voltage(s) ground in the power supply. This would make it extremely difficult to get the electrons to go where you wanted them to, although it might produce a really cool and unique "lighted" PC case. The downside is that it would almost certainly kill the motherboard.
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