Oh yeah, of course, i forgot: mount the pump inline if you don't want its heat to go into your water.
About my 30W+ pump I think a large part of its heat goes into air, thats why it barely changes anything to water temp.
Now, i've no peltier, and i've noticed that ambient temperature will greatly affect the core CPU temp. Just a 2°C drop in ambient can cause a 4°C drop of your CPU temp... Well, thats in my case, where i got an oversized rad.
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