I'd say those temps are about right, maybe just a little high though.
Try a more powerful fan on your radiator, even just temporary, to see if thats a weakness, try remounting your block a couple of times, try a ziptie around a cable to slightly reduce the flow, see what happens.
Your basic setup is very good, you've got good block, pump, rad, but you might need to do a bit of tweaking
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2x P3 1100's at 1400, Abit VP6, 2x Corsair 256mb PC150 sticks, 20gb 'cuda ATA-III, 2x 40gb 'cuda ATA-IV in raid 0. 20" Trinitron. No fans
2x 2400+ at 2288mhz (16.0 x 143), Iwill MPX2, 2x Kingmax PC-3200 256mb sticks, 4x 20gb 60gxp in Raid 5 on a Promise SX6000. Asus Ti4200 320/630. Cooled by Water
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