What surfaces would you be painting? As long as you leave the surfaces that will be contacting your heat source and your coolant alone, you will be fine as far as temps go.
I am sure you could use rustoleum and get good results.
Brian W
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Water Cooled Inwin Q500 (Dual Rads: Rad1 = DTEK Pro Core | Rad2 = Blick Ice Estreme, Hydor L30, Dangerden Maze2, Bay Res Typhoon Reservoir, 1/2 " DD Tygon Thick Wall Hose).
Flow: Res, Pump, CPU watervlock, Y into both rads, both rads into res independently.
Athlon XP 1800+ (@ 1731 - 150mhz fsb.), on a Asus A7N266-c, and a Radeon 9000 *waiting for RMA'd Saphire 9800 ultra from Newegg)
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