Size has little relevance to cooling power. A 40mm TEC could be anything from 10W to 172W. The easiest way to get a rough estimate is to power one up and read how much current it draws, then multiply by voltage*0.7 to get a rough estimate of the cooling power of the TEC. You should test at around 12-15V to get a reasonable reading.
So for instance if you power up at 12V and get 20A current draw. You can do 12*20*0.7 = 168W. And that's roughly the cooling power of your TEC.
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