Water and electronics are NOT a good mix. A well constructed watercooling apparatus, however, will be almost completely leak-proof, and will do much better than any air cooling system will ever do.
I'm running one massive watercooling system on three computers in parallel right now, and a good sized proportion of people here use either watercooling or some other exotic cooling solution.
I would do months of research before considering it, and I would earmark about $300 before jumping into it. You really need to know what you're doing, what parts do better than others and why, and what to expect before you take a step like that. I'd start by getting comfortable with overclocking and then wait at least a few months of heavy research before jumping in. Our FS/FT forum is loaded with people trying to dump watercooling gear because they got in over their head without doing proper research. Don't fall into that trap.
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#!/bin/sh {who;} {last;} {pause;} {grep;} {touch;} {unzip;} mount /dev/girl -t {wet;} {fsck;} {fsck;} {fsck;} {fsck;} echo yes yes yes {yes;} umount {/dev/girl;zip;} rm -rf {wet.spot;} {sleep;} finger: permission denied
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