Unless your over curious don't bother. Keep in mind that if the rad should fail the water will slowly increase in temp. There are plenty of hardpoint to add a thermal probe. If I were to put a probe anywhere it would be on the top of the CPU cooler(only possible on an all copper block, plexi is to insulative). This spot should be the same temp as the coolant inside the cpu block. If you have a fan failure the temps will rise slowly then you could shutoff your comp. Or if the pump fails the water inside the block will rise somewhat quickly and the probe would also detect this and shutdown your comp.
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