The problems outweigh the benefits.
Problems:
#1 If the water isn't pumping BEFORE you turn it on, the chip will mostlikely die.
#2 It will be extremely hard to get it to work properly.
#3 The 'glue' that holds the chip on there is water permeable, you'll have to find a way to insulate it from water, without retaining heat.
#4 Water running over the top of the chip will eventually erode the DIE to nothing.
Benefits:
#1 1-2* C better cooling than the best WB out there...
That's it.
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